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本文报道以环氧溴丙烷作重原子微扰剂,不经除氧,环糊精诱导痕量α-溴代萘的室温磷光。详细讨论了β-CD-EBH-α-BrN形成包接配合物的几种实验条件。结果表明,α-BrN浓度与RTP之间在三个数量级范围内呈良好的线性关系。
This paper reports epibromopropane as a heavy atom perturbation agent, without deoxygenation, cyclodextrine induced trace a-bromonaphthalene room temperature phosphorescence. Several experimental conditions for the formation of inclusion complexes of β-CD-EBH-α-BrN were discussed in detail. The results showed that there was a good linear relationship between the concentration of α-BrN and RTP within three orders of magnitude.