论文部分内容阅读
The synthesis of the title molecule was achieved by the reaction of 2,4-dichlorobenzoyl chloride with potassium thiocyanate in 1:1 molar ratio in dry acetonitrile to afford the corresponding isothiocyante in situ followed by the treatment with 2-aminobiphenyl. The structure of the target compound was established by elemental analysis, FTIR, 1H, 13 C NMR and mass spectroscopy and unequivocally confirmed by the crystallographic data. The title compound crystallizes in the monoclinic space group P21/n with a = 13.356(2), b = 7.0761(11), c = 20.539(3) , β = 105.723(4)°, V = 1868.5(5) 3 and Z = 4.
The synthesis of the title molecule was achieved by the reaction of 2,4-dichlorobenzoyl chloride with potassium thiocyanate in 1: 1 molar ratio in dry acetonitrile to afford the corresponding isothiocyante in situ followed by the treatment with 2-aminobiphenyl. The structure of the The title compound was established by elemental analysis, FTIR, 1H, 13 C NMR and mass spectroscopy and unequivocally identified by the crystallographic data. The title compound crystallizes in the monoclinic space group p21 / n with a = 13.356 (2), b = 7.0761 11), c = 20.539 (3) , β = 105.723 (4) °, V = 1868.5 (5) 3 and Z = 4.