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Two new zinc(Ⅱ) compounds with dibenzoylmethane and N-donor ancillary ligands,[Zn(μ-pyz)(dbm)_2]_n(1) and [Zn(dbm)_2(μ-bpe)Zn(dbm)_2](2)(Hdbm = dibenzoylmethane,pyz = pyrazine and bpe = 1,2-bis(4-pyridyl)ethane),have been prepared and characterized using elemental analysis,IR,~1H NMR and 13 C NMR spectroscopy,and studied by thermal gravimetric analysis as well as single-crystal X-ray diffraction. The crystal and molecular structures of 1 and 2 have been solved by X-ray diffraction and they turned out to be a one-dimensional coordination polymer with linear dispositions of metal atoms and binuclear compound,respectively. These one-dimensional polymers are further connected to form a 3D supramolecular network by C–H···O(only in 2) and π-π interactions.
Two new zinc (Ⅱ) compounds with dibenzoylmethane and N-donor ancillary ligands, [Zn (μ-pyz) (dbm) _2] _n (1) and [Zn (dbm) _2 (μ-bpe) Zn (dbm) _2] (2) (Hdbm = dibenzoylmethane, pyz = pyrazine and bpe = 1,2-bis (4-pyridyl) ethane), have been prepared and characterized using elemental analysis, IR, ~ 1 H NMR and 13 C NMR spectroscopy, and studied by The crystal and molecular structures of 1 and 2 have been solved by X-ray diffraction and they turned out to be one-dimensional coordination polymer with linear dispositions of metal atoms and These one-dimensional polymers are each attached to a 3D supramolecular network by C-H · O (only in 2) and π-π interactions.