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以统计热力学为基础,建立了气体水合物生成条件——分解压力和分解温度的理论计算方法,并对7种以CFC替代工质为蓄冷媒的气体水合物的生成条件进行计算.计算结果与文献报道的实验数据比较吻合
Based on statistical thermodynamics, a theoretical calculation method of gas hydrate formation conditions - decomposition pressure and decomposition temperature was established. The formation conditions of seven kinds of gas hydrates with CFC as substitute refrigerant were calculated. The calculated results are in good agreement with the experimental data reported in the literature