采用HF络合法,通过改进实验条件制得了α-磷酸锆(α-ZrP)微晶.讨论了HF/Zr比,P/Zr比,Zr浓度,玻璃瓶质和反应温度等因素对α-ZrP结晶度和生长形态的影响.发现α-ZrP趋向于生成片状,其片状最大外表面是α-ZrP的层板平面(001),析晶速度的快慢影响该面的面积和厚度.d_(002),d_(110),d_(112)衍射峰的相对衍射强度(XRD结果)与析晶速度有关并与晶体形状(SEM结果)存在着对应关系. The α-ZrP (α-ZrP) crystallites were obtained by the HF complexation method, and the effects of HF / Zr ratio, P / Zr ratio, Zr concentration, glass bottle temperature and reaction temperature on the α- ZrP crystallinity and growth morphology. It is found that the α-ZrP tends to flake, the largest outer surface of the sheet is the α-ZrP lamina plane (001), the speed of the crystallization rate affects the area and thickness of the surface. The relative diffraction intensity (XRD results) of d 002, d 110 and d 112 diffraction peaks are related to the rate of crystallization and correspond to the shape of the crystals (SEM results).