The Canadian journal of Chemical Engineering 1992,70(3):516～522报道在Berty反应器中试验了工业氧化铝和氧化钛基CS_2水解催化剂.在290℃以下活化的铝土矿和在290℃以上氧化钛是具有高活性的催化剂.热重分析指出在300℃左右时,氧化钛中的水完全解吸掉了,而氧化铝和铝土矿即使在550℃以上仍在继续解吸.应用Kelvin方程式预测在这些催化剂孔径上的毛细管凝聚作用时,表明水蒸汽凝聚对于氧化铝催化剂可以忽略,而硫蒸汽会显著将孔 The Canadian journal of Chemical Engineering 1992, 70 (3): 516-522 reported that industrial alumina and titania-based CS2 hydrolysis catalysts were tested in a Berty reactor. Bauxite activated at temperatures below 290 ° C and oxidation above 290 ° C Titanium is a highly active catalyst.Thermal gravimetric analysis shows that at about 300 ℃, the water in titanium oxide is completely desorbed, while alumina and bauxite continue to desorb even above 550 ℃ .The Kelvin equation Capillary coalescence on these catalyst pores indicates that water vapor condensation is negligible for the alumina catalyst whereas sulfur vapor can significantly reduce the pore size