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研究了ＹＣｌ３ＬｉＣｌＯ４ＤＭＳＯ（ 二甲基亚砜） 体系电导率与温度的关系， 及钇在Ｐｔ 和Ｃｕ 电极上的电化学行为。结果表明， Ｙ３ ＋ 在Ｐｔ 和Ｃｕ 电极上可一步不可逆还原为Ｙ， 在铜电极上于－ ２．５００ Ｖ（ｖｓ ＳＣＥ）下恒电位电解， 可获得粘附性好、Ｙ 含量达９７．９ ％ （ 质量分数） 的均匀沉积膜。利用循环伏安法、计时电流法、计时电位法测定了Ｙ３ ＋ 离子在２９８ Ｋ 下， ＹＣｌ３ＬｉＣｌＯ４ＤＭＳＯ 溶液中的扩散系数为３．２２ ×１０ －６ｃｍ２·ｓ－１ ， 电荷传递系数为０．２２ 。
The relationship between conductivity and temperature of YCl3LiClO4DMSO (dimethylsulfoxide) system and the electrochemical behavior of yttrium on Pt and Cu electrodes were studied. The results show that Y3 + can be irreversibly reduced to Y on the Pt and Cu electrodes, and the potential of Y3 + is 97.9 at the potential of -2.500 V (vs SCE) % (Mass fraction) of the uniform deposited film. The diffusion coefficient of YCl3-LiClO4-DMSO solution was 3.22 × 10-6cm2 · s-1 at 298 K by cyclic voltammetry, chronoamperometry and chronopotentiometry. The charge transfer coefficient was 0.22.