物理有机化学诞生于20世纪初叶,是有机化学和物理化学之间学科交叉融合产生的一门有机化学的重要分支学科.物理有机化学旨在运用数学的定量解析和物理学的概念及手段,揭示有机化合物的结构、性能和反应机理等一系列涉及有机物转化的规律性问题.近一个世纪以来,物理有机化学为有机化学从经验走向理性奠定了主要理论基础,至今仍然是促进有机化学理性发展的最具驱动力、最值得关注的重要研究领域之一.合成化学的每一次进步均离不开物理有机研究的强力支持.尤其是进入新世纪以来,伴随着先进仪器分析技术 Physical organic chemistry was born in the early twentieth century, is an important branch of organic chemistry produced by the interdisciplinary integration of organic chemistry and physical chemistry physics organic chemistry aims to use mathematical quantitative analysis and physics concepts and means to reveal Organic compounds, structure, properties and reaction mechanism of a series of regularity issues involving the conversion of organic matter.For nearly a century, physical and organic chemistry for organic chemistry from experience to rationality has laid the main theoretical basis, is still to promote the rational development of organic chemistry The most driving force, the most noteworthy one of the important areas of research.Every progress in synthetic chemistry are inseparable from the strong support of physical and organic research.Especially in the new century, accompanied by advanced instrumental analysis