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聚乙快的不稳定性及难以加工影响了其应用.最近,Naarmann通过陈化在硅油中的Ti(OBu)_4~-AlEt_3催化体系及加入不同量的Li-(n-Bu)制得了拉伸后电导率达10~5S/cm的聚乙炔膜,此膜的电导和形态在空气中几个月几乎不发生改变.我们曾报导用加热的甲苯-Ti(OBu)_4~--AlEt_3催化体系合成高性能聚乙炔膜.本文进一步讨论不同溶剂对高性能聚乙炔(HPPA)合成及性能的影响.
Recently, Naarmann has been prepared by aging the Ti (OBu) 4 AlEt 3 catalyst system in silicone oil and adding different amounts of Li (n-Bu) Stretched polyacetylene film with a conductivity of 10 ~ 5S / cm, the conductance and morphology of the film hardly change in air for several months.We have reported that the catalyst is catalyzed by heated toluene-Ti (OBu) _4 ~ -AlEt_3 System synthesis of high-performance polyacetylene film.This paper further discusses the different solvents on the performance of high performance polyacetylene (HPPA) synthesis and performance.