【摘 要】
：
The title complex, C20H17N4Pd2Cl3·0.5CH3OH, crystallizes in the triclinic system, space group P1 with a = 9.927(6), b = 11.079(6), c = 11.233(6) ?, α = 73.970
【机 构】
：
College of Chemistry and Chemical Engineering,Fujian Normal University,State Key Laboratory of Struc
论文部分内容阅读
The title complex, C20H17N4Pd2Cl3·0.5CH3OH, crystallizes in the triclinic system, space group P1 with a = 9.927(6), b = 11.079(6), c = 11.233(6) ?, α = 73.970(12), β = 85.738(16), γ = 83.300(12)o, V = 1178.1(11)?3, Mr = 648.55, Z = 2, Dc = 1.520 g/cm3, μ = 1.884 mm-1, F(000) = 634, the final R = 0.0460 and wR = 0.1280. This title compound was investigated for the catalytic behavior towards norbornene(NB) vinyl addition polymerization. And the complex exhibits good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.
The title complex, C20H17N4Pd2Cl3 · 0.5CH3OH, crystallizes in the triclinic system with space group P1 with a = 9.927 (6), b = 11.079 (6), c = 11.233 (6) 85.738 (16), γ = 83.300 (12) o, V = 1178.1 (11)? 3, Mr = 648.55, Z = 2, Dc = 1.520 g / cm3, μ = 1.884 mm-1, F , the final R = 0.0460 and wR = 0.1280. And the complex exhibits good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.
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