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阿霉素（ＡＤＭ）在０．１ｍｏｌ／ＬＨＡｃ－ＮａＡｃ底液（ｐＨ４．３），富集电位－０．２０Ｖ（ｖｓ．Ａｇ／ＡｇＣｌ）、富集时间１２０ｓ、扫速１００ｍＶ／ｓ等条件下，于悬汞电极上产生一灵敏的吸附伏安还原峰，峰电位为－０．４５Ｖ，峰电流与ＡＤＭ浓度在１．０×１０－９～４．０×１０－７ｍｏｌ／Ｌ范围内呈线性关系，检测限可达５．０×１０－１０ｍｏｌ／Ｌ。该法用于病人尿样中ＡＤＭ的测定，得到满意的结果。用多种电化学手段研究了阿霉素的伏安行为和反应机理，测定了有关参数。实验表明，体系属可逆吸附波。
Adriamycin (ADM) under the conditions of 0.1mol / L HAc-NaAc (pH4.3), enrichment potential -0.20V (vs.Ag/AgCl), enrichment time 120s and sweep speed 100mV / s , A sensitive adsorption voltammetric reduction peak was generated on the hanging mercury electrode with the peak potential of -0.45V and the peak current and ADM concentration in the range of 1.0 × 10-9 ~ 4.0 × 10-7mol / L Linear relationship, detection limit of up to 5.0 × 10-10mol / L. This method is used in the determination of ADM in patients with urine samples, with satisfactory results. The voltammetric behavior and reaction mechanism of doxorubicin were studied by a variety of electrochemical methods. The relevant parameters were determined. Experiments show that the system is reversible adsorption wave.