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The title cluster compound was synthesized by solid state reaction at low heating temperature. C15H30IMo3N3S13, Mr=1083. 93, monoclinic, P21/n, a = 14.396(3), b = 13. 116(3), c=18. 142(8)A;β= 91. 36(3)°; V =3425(2)A3, Z = 4. Dc = 2. 10g/cm3, F(000) = 2112,μ(MoKa) = 27. 29cm-1, final R = 0. 034, Rw = 0. 051 for 1845 unique observed reflections (I≥3σ(I)). The three Mo atoms form an equilateral triangle with an average side length of 2. 714 A. Each Mo atom is coordinated with seven S atoms forming a distorted pentagonal bipyramid. The iodine atom connects with three S atoms (out of the CMo3] plane) with an average distance of 3. 205 A.The title compound has similar cubane-like cluster core [Mo3S7I] as the compound Mo3(μ3-S)(μ2-S2)3(dtp)3I(dtp= (EtO)2PS2).
The title cluster compound was synthesized by a solid state reaction at a low heating temperature. C15H30IMo3N3S13, Mr = 1083.93, monoclinic, P21 / n, a = 14.396 (3), b = 13.116 (8) A; β = 91. 36 (3) °; V = 3425 (2) A3, Z = 4. Dc = 2. 10g / cm3, F -1, final R = 0. 034, Rw = 0. 051 for 1845 unique observed reflections (I ≥ 3σ (I)). The three Mo atoms form an equilateral triangle with an average side length of 2. 714 A. Each Mo atom is coordinated with seven S atoms forming a distorted pentagonal bipyramid. The iodine atom connects with three S atoms (out of the CMo3] plane) with an average distance of 3. 205 A. The title compound has similar cubane- Mo3S7I] as the compound Mo3 (μ3-S) (μ2-S2) 3 (dtp) 3I (dtp = (EtO) 2PS2).