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The crystal structure of the title complex, [Cu(C23H26N2)Cl2]2·2CH2Cl2, has been determined by single-crystal, X-ray diffraction techniques. The compound crystallizes as dark-green prisms in space group P21/c of the monoclinic system, with Z=4 and unit cell dimensions a=1.710 9(7) nm, b=2.395 2(11) nm, c=1.348 9(6) nm and β=110.651(8)°. The complex consists of two similar but crystallographically independent dimers, of which Cu(Ⅱ) centers display five-coordinated trigonal-bipyramidal geometry with Cu-Cu separations in two centrosymmetric dimers are 0.345 1 and 0.347 8 nm, respectively, and in each dimer the two copper centers share a common edge formed by two bridging chloride ions, each being equatorial. Solvent molecules of CH2Cl2 are packed together in the crystal lattice. CCDC: 253299.
The crystal structure of the title complex, [Cu (C23H26N2) Cl2] 2.2CH2Cl2, has been determined by single-crystal, X-ray diffraction techniques. The compound crystallizes as dark-green prisms in space group P21 / c of the monoclinic system with Z = 4 and unit cell dimensions a = 1.710 9 (7) nm, b = 2.395 2 (11) nm, c = 1.348 9 (6) nm and β = 110.651 (8) °. The complex consists of two like but crystallographically independent dimers, of which Cu (II) centers display five-coordinated trigonal-bipyramidal geometry with Cu-Cu separations in two centrosymmetric dimers are 0.345 1 and 0.347 8 nm, respectively, and in each dimer the two copper centers share a Common edge formed by two bridging chloride ions, each being equatorial. Solvent molecules of CH2Cl2 are packed together in the crystal lattice. CCDC: 253299.