论文部分内容阅读
Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets.A three dimensional heteronuclear Mn-Na compound [MnNa(N3)4(C5H5N)4] was obtained by reaction of [Mn3O(O2CCH3)6(py)3]ClO4 and NaN3 in pyridine solvents.The title compound crystallizes in monoclinic space group C2/c,a=1.536 6(2),b=1.045 3(2),c=1.576 3(2) nm,β=90.309(3)°,V=2.531 8(6) nm3,Z=4.In the structure,each Mn3+ and Na+ ion coordinated with four N atoms from four N3-and two N atoms from two pyridine molecules.Each pair of Mn3+ and Na+ ion are linked by N3-bridges into a 3D polymer with PtS topology.CCDC:706250.
Azide-containing coordination polymers have received attention for the construction of new molecule-based magnets. A three-dimensional heteronuclear Mn-Na compound [MnNa (N3) 4 (C5H5N) 4] was obtained by reaction of [Mn3O (O2CCH3) py) 3] ClO4 and NaN3 in pyridine solvents. The title compound crystallizes in monoclinic space group C2 / c, a = 1.536 6 (2), b = 1.045 3 90.309 (3) °, V = 2.531 8 (6) nm3, Z = 4.In the structure, each Mn3 + and Na + ion coordinated with four N atoms from four N3- and two N atoms from four pyridine molecules .ach pair of Mn3 + and Na + ion are linked by N3-bridges into a 3D polymer with PtS topology. CCDC: 706250.