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环氧化物转化为β－卤代醇的简便方法ＫｏｔｓｕｋｉＨ等［ＴｅｔｒａｈｅｄｒｏｎＬｅｔｔ，１９９６；３７：１８４５］附于硅胶上的卤化锂在无水ＣＨ２Ｃｌ２中能有效地将环氧化物转化为β－卤代醇。反应活性ＬｉＩ＞ＬｉＢｒ＞＞ＬｉＣｌ。反应简单高效，条件温和，８...
A Simple Method for the Conversion of Epoxides to β-Halohydrins The lithium halide attached to silica gel in Kotsuki H et al [Tetrahedron Lett, 1996; 37: 1845] effectively converts epoxides to β-halohydrins . Reactive LiI> LiBr >> LiCl. The reaction is simple and efficient, mild conditions, 8 ...