Density functional calculations have been performed to investigate the adsorption of twenty two different kinds of metal adatoms on graphene-like BC3.In contrast to the graphene adsorbed with adatoms,the BC3 with adatoms shows many interesting properties.(1)The interaction between the metal adatoms and the BC3 sheet is remarkably strong.The Li,Na,K,and Ca possess the binding energies larger than the cohesive energies of their corresponding bulk metals.(2)The Li,Na,and K adatoms form approximately ideal ionic bonds with BC3,while the Be,Mg,and Ca adatoms form ionic bonds with BC3 with slight hybridization of covalent bonds.The Al,Ga,In,Sn,and all transition metal adatoms form covalent bonds with BC3.(3)For all the structures studied,there exhibit metal,half-metal,semiconducting,and spin-semiconducting behaviors.Especially,the BC3 with Co adatom shows a quantum anomalous Hall(QAH)phase with a Che number of -1 based on local density approximation calculations.(4)For Li,Na,K,Ca,Ga,In,Sn,Ti,V,Cr,Ni,Pd,and Pt,there exists a trend that the adatom species with lower ionization potential have lower work function.Our results indicate the potential applications of functionalization of BC3 with metal adatoms.