Post-functionalization of disubstituted polyacetylenes via click chemistry

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：nanfangjituan

【摘要】

：

我们报导一个合成图案和 disubstituted polyacetylenes 的准备的试验性的探索(舞步， P3 ) 通过有忍受炔属羟 pendants 的先锋 PA 的叠氮化物的 1,3-dipolar cycloaddition。

【作者】

：

TONG Li QIN AnJun ZHANG XiaoA

【机构】

：

InstituteofBiomedicalMacromolecules,DepartmentofChemistry

【出处】

：

中国科学：化学英文版

【发表日期】

：

2011年12期

【关键词】

：

聚乙炔化学功能化核磁共振光谱偶极环加成三甲基硅烷 PAS 叠氮化物 disubstituted polyacetylene click chemis

【基金项目】

：

partially supported by the National Natural Science Foundation of China (21074113,20634020 & 20974028),the National Basic Research Program of China (973 Program,2009CB623605),the Research Grants C

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我们报导一个合成图案和 disubstituted polyacetylenes 的准备的试验性的探索(舞步， P3 ) 通过有忍受炔属羟 pendants 的先锋 PA 的叠氮化物的 1,3-dipolar cycloaddition。先锋 PA (P2 ) 被太古的 PA 的 desilylation 与 trimethylethynylsilane 方面链(P1 ) 导出。P1 被双炔属羟的包含单体的聚合在 WCl6-Ph4Sn 催化剂的提升下面与由 trimethylsilane (M) 盖住结束

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Post-functionalization of disubstituted polyacetylenes via click chemistry

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