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K+-SrO-La2O3/ZnO(KSLZ)催化体系具有很好的催化活性.在1073K反应温度下,其C2产率为18.2%,且C2选择性为68.3%.催化剂抗潮能力明显增加,在室温下经长期放置后,催化剂活性稳定.用XRD,CO2-TPD和XPS表征了KSLZ催化剂的体相组成及表面碱性、表面组成和表面活性氧物种.在此基础上讨论了La2O3,SrO和K+各组分对甲烷氧化偶联反应的作用,提出了表面碳酸盐分解生成活性氧物种的可能性.
K + -SrO-La2O3 / ZnO (KSLZ) catalytic system has good catalytic activity. At a 1073K reaction temperature, its C2 yield was 18.2% and the C2 selectivity was 68.3%. The moisture resistance of the catalyst is obviously increased. The catalyst has stable activity after being stored at room temperature for a long time. The phase composition, surface alkalinity, surface composition and surface active oxygen species of KSLZ catalyst were characterized by XRD, CO2-TPD and XPS. On this basis, the effects of La2O3, SrO and K + on the oxidative coupling reaction of methane were discussed, and the possibility of decomposition of surface carbonate to generate reactive oxygen species was proposed.