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采用选择离子监测(SIM)模式作为气相色谱/质谱法(GC/MS)检测方式测定了某超高压液压油中两种添加剂2,6-二叔丁基对甲酚的质量比和磷酸三苯酯的质量比。测得的校正因子F值和添加剂质量比均有较高的精确度。还对SIM 模式中有关离子的选择作了简单的探讨。
The mass ratio of 2,6-di-tert-butyl-p-cresol and two kinds of additives in an ultrahigh-pressure hydraulic oil were determined by selective ion monitoring (SIM) mode as gas chromatography / mass spectrometry (GC / MS) Ester mass ratio. Measured correction factor F value and additive mass ratio have higher accuracy. The selection of ions in the SIM mode is also briefly discussed.