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At room temperature, dibenzoyl peroxide undergoes oxidative addition reaction with metallic copper powder and 4 dimethylamine pyridine which affords the last products as binuclear copper?complex (1), [Cu(C6H5COO)2(C7H10N2)]2. This complex is further characterized by spectroscopic methods. The structure of complex (1) has been determined by a single crystal X ray analysis. Crystallographic data are as follows: monoclinic, space group P21/n, a=10.446(2)?, b=11.140(5)?, c=17.179(3)?, β=95.92(3)°, V=1988.4(7)?3, Z=4, F(000)=884, μ=11.27cm-1, D(calcd.)=1.429g·cm-3, R=0.0399, Rw=0.1202. Each copper?ion is coordinated by two bridging bidentate benzoate and 4 dimethylamine pyridine to form dimeric molecule. CCDC: 188744.
At room temperature, dibenzoyl peroxide undergoes oxidative addition reaction with metallic copper powder and 4-methylamine pyridine which affords the last products as binuclear copper? Complex (1), [Cu (C6H5COO) 2 (C7H10N2)] 2. This complex is further characterized by The structure of complex (1) has been determined by a single crystal X ray analysis. Crystallographic data are as follows: monoclinic, space group P21 / n, a = 10.446 (2) ?, b = 11.140 , β = 95.92 (3) °, V = 1988.4 (7) 3 3, Z = 4, F (000) = 884, μ = 11.27 cm -1, D calcd. 1.429 g · cm -3, R = 0.0399, Rw = 0.1202. Each copper ion is coordinated by two bridging bidentate benzoate and 4 dimethylamine pyridine to form dimeric molecule. CCDC: 188744.