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Synthesis of highly strained tetracyclic ketones was achieved by cyclopropanation or epoxidation of tricyclodecenone 1. An unusual formation of α-methoxy β-hydroxy ketone from an α，β-unsaturated enone system via Payne rearrangement was reported.
Synthesis of highly strained tetracyclic ketones was achieved by cyclopropanation or epoxidation of tricyclodecenone 1. An unusual formation of α-methoxy β-hydroxy ketone from an α, β-unsaturated enone system via Payne rearrangement was reported.