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在一定研究基础上合成出分子式为{Ag(hpb)(ClO_4)_2[(CH_3)_2CO]_2}1(hpb=C_6Ph_6)的二核银配合物,并制备出自由配体hpb的单晶2,其结构由X射线单晶衍射表征.将这两种化合物与先前研究结果比较发现,配合物的分子空间结构不仅依赖于阴离子大小、溶剂性质,还取决于溶剂类型和自由配体的分子空间结构与排列,并且这种结构变化导致了导电性的不同.
The binuclear silver complex of {Ag (hpb) (ClO_4) _2 [(CH_3) _2CO] _2} 1 (hpb = C_6Ph_6) was synthesized on the basis of previous studies and a single crystal 2 , The structure of which is characterized by X-ray single crystal diffraction.The comparison of these two compounds with the previous results shows that the molecular structure of the complex depends not only on the size of the anion and on the nature of the solvent but also on the type of solvent and the molecular space of the free ligand Structure and arrangement, and this structural change leads to the difference of conductivity.