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Tricyclopentylgallium reacted with phenol, naphthol respectively to yield phenox-ide (or naphthoxide) of biscyclopentylgallium which have been characterized by elemental analysis, IR, 1H NMR and mass spectrometry. X-ray diffraction analysis of compound 1 indicated that it belongs to the monoclinic system, space groups P21/c, with cell constants 0=9.602(3), 6=14.365(7), c=11.256(4)A, and β=97.54(3)°, Z=2(dimers), R=0.0706. Compound 2 assigned to the triclinic system, space groups P1 with cell constants a=9.392(4), 6=9.928(7), c=11.263(7) A, a=112.48(5), β=104.74(4), γ=99.95(5)°, and Z=l(dimers), R=0.0526. The molecule of 1 or 2 contains an oxygen-bridged coplanar Ga2O2 four-membered ring respectively.
Tricyclopentylgallium reacted with phenol, naphthol respectively to yield phenox-ide (or naphthoxide) of biscyclopentylgallium which have been characterized by elemental analysis, IR, 1H NMR and mass spectrometry. X-ray diffraction analysis of compound 1 indicates that it belongs to the monoclinic system , space groups P21 / c, with cell constants 0 = 9.602 (3), 6 = 14.365 (7), c = 11.256 (4) A and β = 97.54 (3) °, Z = 0.0706 Compound 2 assigned to the triclinic system, space groups P1 with cell constants a = 9.392 (4), 6 = 9.928 (7), c = 11.263 (7) A, a = 112.48 (5), β = 104.74 ), γ = 99.95 (5) °, and Z = l (dimers), R = 0.0526. The molecule of 1 or 2 contains an oxygen-bridged coplanar Ga2O2 four- membered ring respectively.