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本文介绍了几位作者所合成并用X射线单晶结构分析表征的五类新型Fe,Co,Ru羰基簇合物。讨论其成键方式与结构特点。并介绍某些具有双键的配位基以不同的断裂方式提供不同的分子片配位于原子簇骨架的情况。
In this paper, we introduce five novel Fe, Co, Ru carbonyl clusters synthesized by several authors and characterized by X-ray single crystal structure analysis. Discuss its key forming method and structure. And some ligands with double bonds are introduced to provide different molecular fragments for coordination in the framework of atomic clusters with different breaking modes.