【摘 要】
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Polarization of a high-energy exciton in conjugated polymers is investigated theoretically by using an extended one-dimensional tight-binding Su-Schrieffer-Heeg
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Polarization of a high-energy exciton in conjugated polymers is investigated theoretically by using an extended one-dimensional tight-binding Su-Schrieffer-Heeger(SSH)model.Under an exteal electric field,the reverse polarization of a high-energy exciton is obtained and the corresponding physical mechanism is analyzed.A critical field Ec is obtained,over which the polarization of the high-energy exciton will switch from negative to positive.In addition,by taking into account the effect of the non-degenerate confinement,we find that it is possible to realize reverse polarization through high energy photoexcitation in non-degenerate polymers.
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