The exact radar cross-section (RCS) measurement is difficult when the scattering of targets is low. Ful polarimetric cali-bration is one technique that offers the potential for improving the accuracy of RCS measurements. There are numerous polarimetric calibration algorithms. Some complex expressions in these algo-rithms cannot be easily used in an engineering practice. A radar polarimetric coefficients matrix (RPCM) with a simpler expression is presented for the monostatic radar polarization scattering matrix (PSM) measurement. Using a rhombic dihedral corner reflector and a metal ic sphere, the RPCM can be obtained by solving a set of equations, which can be used to find the true PSM for any target. An example for the PSM of a metal ic dish shows that the proposed method obviously improves the accuracy of cross-polarized RCS measurements.