近年来各种膦桥过渡金属双核配合物由于其特殊的结构,新奇的反应性能及催化行为,受到了人们的普遍关注。对它们的研究已成为有机金属化学的一个前沿领域。其中含膦的三原子桥联双核物(以下简称膦桥双核物)尤为重要,本文将对这类化合物的合成、结构以及催化行为研究现状加以综述。 In recent years, various phosphine bridged transition metal binuclear complexes have attracted people’s attention due to their special structure, novel reaction properties and catalytic behavior. Their research has become a frontier area of ​​organometallic chemistry. Among them, phosphine-containing triatomic bridged binuclear species (hereinafter referred to as phosphine bridge binuclear species) are of particular importance. In this paper, the synthesis, structure and catalytic behavior of these compounds are reviewed.