报道了在 L ewis酸促进下三丁基烯丙基锡与芳香酰腙合成 N -烯丙基芳香酰肼的一种新型的亲电加成反应。合成了 7个未见文献报道的新化合物。其结构均经 IR,1H NMR,13C NMR,MS确证。该反应条件温和 (室温即可进行 ) ,选择性高 ,产率 5 0 %～ 6 0 %。以酰腙和三丁基烯丙基锡摩尔比为 1∶ 2的反应也发现只有在 C=N上加成 ,而 -C(=O) -没有发生变化。 A novel electrophilic addition reaction of tributyl allyltin with aromatic acylhydrazone to N - allyl aromatic hydrazide catalyzed by Lewis acid was reported. Seven new compounds have not been reported in the literature. The structures were confirmed by IR, 1H NMR, 13C NMR and MS. The reaction conditions are mild (room temperature can be carried out), high selectivity, the yield of 50% to 60%. The reaction with a molar ratio of acylhydrazone to tributyl allyltin of 1: 2 also found that only C = N was added while -C (= O) - did not change.