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本文报道了担载四核羰基钻簇Co_4(CO)_8(μ_2-CO)2(μ_4-P-)-2_/(P)(2)[(P):聚(苯乙烯-二乙烯基苯)]的合成。2的钴含量为9.5%。用X光电子能谱测定,2的Co(2p_(3/2))电子结合能比Co_4(CO)_8(μ_2-CO)_2(μ_4-PPh)_2的高。本文研究了2催化己烯-1的醛化反应。在一定条件下,己烯-1的转化率可达83%,它对醛的选择性约为100%。
In this paper, the effects of loading tetranuclear carbonyl cluster Co_4 (CO) _8 (μ_2-CO) 2 (μ_4-P -) - 2 _ / (P) )]Synthesis. 2 cobalt content of 9.5%. The X-ray photoelectron spectroscopy showed that the electron binding energy of 2 (2p_ (3/2)) was higher than that of Co_4 (CO) _8 (μ_2-CO) _2 (μ_4-PPh) _2. In this paper, 2-catalyzed allylation of hexene-1 was studied. Under certain conditions, the conversion of hexene-1 can reach 83%, its selectivity to aldehyde is about 100%.