导电聚合物兼具有机聚合物的性能及半导体和金属的电性能。大多数导电聚合物材料是采用三种方法制造的。第一种力法是,将大的片状或粒状导电材料,如金属片和碳黑粒混入聚合物母体中,制成导电复合材料。目前市面上多数导电聚合物产品采用此法制造。第二种方法是,将给电子或受电子掺杂剂加入高度共轭的体系中,这种导电聚合物的导电性受掺杂剂用量的制约,并因其用量的不同而异。第三种方法是,采用热解法改变聚合物固有的基本性能。材料的导电性(σ)取决于载流子的浓度(n)、它们的电荷(e)和迁移率(u),即,σ=neu。对于聚合物导电材料虽有广泛研究,但尚无好的导电性理论模型或聚合物结构与导电率之间的实验关系。主要问题是,现有模型 Conductive polymers combine the properties of organic polymers with the electrical properties of semiconductors and metals. Most conductive polymer materials are manufactured using three methods. The first is that large sheet or granular conductive materials, such as metal and carbon black particles mixed into the polymer matrix, made of conductive composite material. Currently on the market most of the conductive polymer products using this method of manufacturing. The second method is to add electron or electron dopants to a highly conjugated system. The conductivity of such conductive polymers is limited by the amount of dopant and varies depending on the amount used. The third method is to use pyrolysis to change the inherent properties of the polymer. The conductivity (σ) of the material depends on the carrier concentration (n), their charge (e) and mobility (u), ie σ = neu. Although extensive research has been conducted on polymer conductive materials, there is no good theoretical model of conductivity or an experimental relationship between polymer structure and electrical conductivity. The main problem is that the existing model