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用气液色谱法研究过一系列作为Lewis碱(B)的有机配体和作为Lewis酸(A)的配合物之间的加合作用.研究较多的碱已有脂肪醇、醚、酮、醛、脂及胶等.对生物体系中广为存在的杂环配体碱的工作还很少.本文着重研究噻吩,呋喃和吡咯这类小分子杂环配体和Ni[CF_3COCHC(C_4H_4S)=NCH_2]_2(以下简称A)配合物的加合反应. Ni[CF_3COCHC(C_4H_4S)=NCH_2]_2的合成参考文献.固定液角鲨烷系英国进口,
Addition of a series of organic ligands as Lewis base (B) and complex as Lewis acid (A) has been studied by gas-liquid chromatography. More bases have been studied for the presence of fatty alcohols, ethers, ketones, Aldehydes, lipids and gums, etc. There are still few work on heterocyclic ligand bases widely present in biological systems.In this paper, we focus on the study of the small heterocyclic ligands such as thiophene, furan and pyrrole and Ni [CF_3COCHC (C_4H_4S) = NCH_2] _2 (hereinafter referred to as A) complex.Relation of the synthesis of Ni [CF_3COCHC (C_4H_4S) = NCH_2] _2. The stationary phase squalane is imported from the United Kingdom,