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在平面正方形和八面体络合物中,内界取代反应的方向基本上决定于配位体和中心原子间键的牢固性,对一系列络合物形成体来说,也决定于在一个座标轴上的配位体的相互影响即反位效应。对于三价钴络合物内单齿配位体的反位活性,近些年来И.И.ЧернЯев,A.B.Аблов,A.B.Бабаева等做过较多的研究。但文献上还极少关于三价钴络合物内环状配位体的反位效应和反位效应对于络合环牢固性影响的报导,关于这方面也就是本工作
In planar squares and octahedral complexes, the orientation of the internal substitution reaction depends essentially on the firmness of the ligand and central atom bonds, and for a series of complex-forming entities, The interaction of the ligands on the scale axis is the anti-bit effect. For the anti-position activity of monodentate ligands in trivalent cobalt complexes, more studies have been done by И.И.ЧернЯев, A.B.Аблов, A.B.Бабаева and others in recent years. However, there is still a paucity of reports on the effect of the anti-position and anti-position effect of the cyclic ligands in the trivalent cobalt complex on the robustness of the complex ring in the literature,