论文部分内容阅读
测定了3种氮氧自由基与环糊精相互作用的EPR波谱,计算了波谱参数,结果表明:与环糊精作用后,自由基的超精细分裂常数aN值及旋转相关时间τc都有规律变化,由此探讨了氮氧自由基与环糊精作用位点及作用力大小。
The EPR spectra of three kinds of nitroxides interacting with cyclodextrins were determined and the spectral parameters were calculated. The results showed that there was a regular pattern of the aN values of the hyperfine splitting constants and the spin-related time τc Changes, which explored the role of nitrogen and oxygen free radicals and cyclodextrin sites and force size.