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介绍了在1300℃下,以BaCO_3-BaF_2-MnCO_3系熔剂对Si含量不同的锰铁合金进行氧化脱磷的实验情况。结果表明,在该实验条件下,当脱磷剂用量分别为100g/kg合金和130-150g/kg合金时,合金中初始硅含量分别对应限制到[%Si]_i≤0.15%和[%Si]≤0.28%,可得到脱磷率η_p>40%、锰氧化损失△[%Mn]<0.5%。通过测定脱磷剂中SiO_2含量对相应渣系的磷酸盐容量C_p的影响关系:lgC_p=26.996-0169(%SiO_2)估算得到.对应上述硅含量[%Si]的限制值,相应渣系磷酸盐容量的限制范围为lgC_p≥26.32或(%SiO_2)≤4%。
The experiment of oxidative dephosphorization of ferromanganese with different Si contents with BaCO_3-BaF_2-MnCO_3 flux at 1300 ℃ was introduced. The results show that under the experimental conditions, when the amount of dephosphorization agent is 100g / kg alloy and 130-150g / kg alloy, the initial silicon content in the alloy is limited to [% Si] _i≤0.15% and [% Si ] ≤0.28%, dephosphorization rate η_p> 40%, manganese oxidation loss △ [% Mn] <0.5% can be obtained. The effect of SiO 2 content in dephosphorization agent on the phosphate capacity C_p of the corresponding residue system was estimated: lgC_p = 26.996-0169 (% SiO_2). Corresponding to the limit value of the above silicon content [% Si], the limit of the corresponding slag system phosphate capacity is lgC_p≥26.32 or (% SiO_2) ≤4%.