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我们从μ-联硫六羰基二铁起始,通过与苯基锂的还原加成及反应中间体对卤代烃的亲核取代反应,成功地合成了(1)至(Ⅵ)六个(μ-苯硫)(μ-烃硫)六羰基二铁络合物。反应式如下:
We have successfully synthesized six (1) to (VI) (1) to (Ⅵ) by reductive addition with phenyllithium and nucleophilic substitution reaction of halogenated hydrocarbons with μ- μ-phenylthio) (μ-hydrocarbon sulfur) hexacarbonyl di-iron complex. The reaction is as follows: