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An aminophenol ligand, N,N,N′-tri(2-hydroxy-5-methylbenzyl)-1,2-ethanediamine, was prepared through the Mannich reaction, and structurally characterized by NMR, IR, MS and single-crystal X-ray diffraction. The title compound (C26H32N2O3, Mr = 420.54) belongs to the monoclinic system, space group P21/n with a = 8.6233(14), b = 10.2655(16), c = 26.017(4) ′, β = 95.797(2)o, V = 2291.3(6) ′3, Z = 4, the final R = 0.0461 and wR = 0.1139 for 4267 unique reflections (Rint = 0.028) with 11691 observed ones (I > 2σ(I)).
An aminophenol ligand, N, N, N’-tri (2-hydroxy-5-methylbenzyl) -1,2-ethanediamine, was prepared through the Mannich reaction, and structurally characterized by NMR, IR, MS and single- The title compound (C26H32N2O3, Mr = 420.54) belongs to the monoclinic system, space group P21 / n with a = 8.6233 (14), b = 10.2655 (16), c = 26.017 (4) ’, (2) o, V = 2291.3 (6) ’3, Z = 4, the final R = 0.0461 and wR = 0.1139 for 4267 unique reflections (Rint = 0.028) with 11691 observed ones (I> 2σ (I)).