Ion diffusion kinetics,depending on the size,tortuosity,connectivity of the channels,greatly affects the rate performance of the electrodes.Two-dimensional materials (2DMs) has emerged as promising electrode materials in the past decades.However,the applications of 2DMs electrodes are limited by the strong restacking problem,which leads to a poor rate capability.In this work,we for the first time mediated the morphology of molybdenum disulfide (MoS2) nanosheets via a facile coagulation method;abundant sheet crumples were induced,which greatly enhance their surface accessibility and thus benefit the ion diffusion kinetics.Consequently,the crumpled-MoS2 electrodes follow a capacitive Na-ion charge-storage mechanism to a large extent.Importantly,we demonstrate the special role of organic cations in the inter-sheet assembly configuration,in sharp contrast with that of alkali/alkaline-earth ones.We propose that organic cations cause edge/face contact of the sheets,instead of the face/face contact,thus affording a house-of-cards structure.