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Pseudo-first order reaction rate constants of 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo (F_(15)CMn(V)-oxo),5,15-bis(pentafluorophenyl)-10-(phenyl)corrole Mn(V)-oxo(F_(10)CMn(V)-oxo),5,15- bis(phenyl)-10-(pentafluorophenyl)corrole Mn(V)-oxo(F_5CMn(V)-oxo) and 5,10,15-tris(phenyl)corrole Mn(V)-oxo(F_0CMn(V)-oxo) with a series of alkene substrates in different solvents were determined by UV-vis spectroscopy.The results indicated that the oxygen atom transfer pathway between Mn(V)-oxo corrole and alkene is solvent-dependent.
Pseudo-first order reaction rate constants of 5,10,15-tris (pentafluorophenyl) corrole Mn (V) -oxo (F_ (15) CMn (V) phenyl) corrole Mn (V) -oxo (F_ (10) CMn (V) -oxo), 5,15- bis (phenyl) -10- (pentafluorophenyl) ) and 5,10,15-tris (phenyl) corrole Mn (V) -oxo (F_0CMn (V) -oxo) with a series of alkene substrates in different solvents were determined by UV-vis spectroscopy.The results indicated that the oxygen atom transfer pathway between Mn (V) -oxo corrole and alkene is solvent-dependent.