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设计合成以4-甲基苯基-6-苯基-2,2′-二联吡啶为主配体、芳炔为辅助配体的铂(II)络合物1-3.与苯乙炔、萘乙炔为辅助配体的络合物1,2相比,蒽乙炔4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物MLCT激发态的能量升高.
Design and synthesis of 4-methylphenyl-6-phenyl-2,2’-bipyridine pyridine as the main ligand, aromatic alkyne ligands for the platinum (II) complex 1-3 with phenylacetylene, Anthracene acetylene 4- (4-methylphenyl) -6-phenyl-2,2’-dipyridylplatinum (II) complex MLCT The energy of the excited state increases.