Amino-Konjacglucomannan(NH2-KGM) was prepared through the reaction of ammonium hydroxide with KGM by ultrasonic. The influence of amount of ammonium hydroxide, concentration of KGM and ultrasonic time on the extent of amination was studied. Then, NH2-KGM and zinc sulfate were used as materials for the preparation of NH2-KGM-Zn complex. The results indicated that the extent of amination increases with increasing the ammonium hydroxide. The optimum concentration of KGM and ultrasonic time are 0.3% and 75 min respectively. IR showed KGM is successfully aminated and NH2-KGM forms stable complex with zinc(Ⅱ). The hydrogen bonding network structures of NH2-KGM-Zn are more stable and the key linking points of hydrogen bonding network are at the OH(6) and O(3) positions of mannose and OH(2) of glucose and O(3) of mannose on the KGM ring. It is more favorable for NH2-KGM-Zn to form intermolecular hydrogen bonds between KGM. Amino-Konjacglucomannan (NH2-KGM) was prepared through the reaction of ammonium hydroxide with KGM by ultrasonic. The influence of amount of ammonium hydroxide, concentration of KGM and ultrasonic time on the extent of amination was studied. Then, NH2-KGM and zinc sulfate were used as materials for the preparation of NH2-KGM-Zn complex. The results indicated that the extent of a determination increases with increasing the ammonium hydroxide. The optimum concentration of KGM and ultrasonic time are 0.3% and 75 min respectively. is successfully aminated and NH2-KGM forms stable complex with zinc (II). The hydrogen bonding network structures of NH2-KGM-Zn are more stable and the key linking points of hydrogen bonding networks are at the OH (6) and O (3 ) positions of mannose and OH (2) of glucose and O (3) of mannose on the KGM ring. It is more favorable for NH2-KGM-Zn to form intermolecular hydrogen bonds between KGM.