本文综述了烯烃氢甲酰化反应的催化剂从钴配合物到铑配合物和从均相催化体系到两相催化体系的发展过程。比较了三种催化剂和两个催化体系的特点、应用情况及研究工作进展. This article reviews the development of catalysts for the hydroformylation of olefins from cobalt complexes to rhodium complexes and from homogeneous catalytic systems to two-phase catalytic systems. The characteristics, applications and progress of the three catalysts and two catalytic systems were compared.