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采用中和转化法制备锑白 (Sb2 O3) ,并用 XRD,IR和 SEM等方法分析测试了产物结构形貌 .从结晶化学角度 ,结合负离子配位多面体生长基元理论探讨了酒石酸根离子对锑白结构形貌的控制规律 .认为酒石酸根离子的强配位能力使溶液中生长基元由 Sb O3E配位四面体转化为 Sb O3+3E星状配位体是立方晶型锑白形成的主要原因 .
The antimony white (Sb 2 O 3) was prepared by the neutralization conversion method, and the structure of the product was analyzed by XRD, IR and SEM etc. The effect of tartaric acid ion on the antimony The control law of the structure of the white structure is that the strong coordination ability of the tartrate ion is that the growth element in the solution is converted from the Sb O3E coordination tetrahedron to the Sb O3 +3 E star ligand, which is the main formation of the cubic antimony white the reason .