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The title compound 1,4,23,26,29,48-hexaaza-6,9:16,19:31,34:41,44-tetrabenzo-12, 15,37,40-tetraoxa-cyclodotetracontane-4,5,18,19,25,26,39,40-octaene 1 (C40H46N6O4) was synthe- sized by [2+2] condensation of diethylenetriamine with 4,4?diformyl-diphenoxyethane (dialdehyde) in a mixed solvent of ethanol and tetrahydrofuran. The crystal data are: Mr = 674.83, triclinic, P, a = 5.8249(1), b = 9.4114(8), c = 17.649(2) ? a = 79.310(7), b = 85.397(4), g = 78.970(8), V = 932.1(1) ?, Z = 1, Dc = 1.202 g/cm3, F(000) = 360, m(MoKa) = 0.079 mm-1, R = 0.0486 and wR = 0.1439. The title molecule has a crystallographic center symmetry. The distance between the two secondary amine nitrogen atoms is 18.890(3) ?
The title compound 1,4,23,26,29,48-hexaaza-6,9: 16,19: 31,34: 41,44-tetrabenzo-12,15,37,40-tetraoxa-cyclodotetracontane-4,5 , 18,19,25,26,39,40-octaene 1 (C40H46N6O4) was synthe- sized by [2 + 2] condensation of diethylenetriamine with 4,4? Diformyl-diphenoxyethane (dialdehyde) in a mixed solvent of ethanol and tetrahydrofuran The crystal data are: Mr = 674.83, triclinic, P, a = 5.8249 (1), b = 9.4114 (8), c = 17.649 (2)? A = 79.310 (7), b = 85.397 = 78.970 (8), V = 932.1 (1) ?, Z = 1, Dc = 1.202 g / cm3, F (000) = 360, m (MoKa) = 0.079 mm-1, R = 0.0486 and wR = 0.1439. The title molecule has a crystallographic center symmetry. The distance between the two secondary amine nitrogen atoms is 18.890 (3)?