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A new polyoxomolybdate compound [Zn(HL)2(Mo8O26)(4,4’-Bipy)]·(4,4’-Bipy) (HL = 3-(2-pyridyl)pyrazole, 4,4’-Bipy = 4,4’-bipyridine) 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, TG and IR spectroscopy. The compound crystallizes in monoclinic, space group C2/c with a = 18.060(4), b = 13.870(3), c = 19.360(4) , β = 93.50(3)°, V = 4840.5(17) 3, C36H30Mo8N10O26Zn, Mr = 1851.59, Dc = 2.541 g/cm3, μ(MoKα) = 2.589 mm·1, F(000) = 3560, Z = 4, the final R = 0.0328 and wR = 0.0870 for 4005 observed reflections (I > 2σ(I)). X-ray diffraction analyses reveal that compound 1 is constructed from Mo8O264-units linked by Zn(HL)22+ and 4,4’-Bipy. Mo8O264-is connected by Zn(HL)22+ via terminal oxygen atoms along the [010] axis forming chains, which are further linked by 4,4’-Bipy along the [001] axis forming a two-dimensional network structure.
A new polyoxomolybdate compound [Zn (HL) 2 (Mo8O26) (4,4’-Bipy)] (4,4’-Bipy) 4,4’-bipyridine 1 has been hydrothermally synthesized synthetically characterized by single-crystal X-ray diffraction, elemental analyzes, TG and IR spectroscopy. The compound crystallizes in monoclinic space group C2 / c with a = 18.060 (4) , b = 13.870 (3), c = 19.360 (4) β, β = 93.50 (3) °, V = 4840.5 (17) 3, C36H30Mo8N10O26Zn, Mr = 1851.59, Dc = 2.541 g / cm3, = 2.589 mm · 1, F (000) = 3560, Z = 4, the final R = 0.0328 and wR = 0.0870 for 4005 observed reflections (I> 2σ (I)). X-ray diffraction analyzes reveal that compound 1 is constructed from Mo8O264-units linked by Zn (HL) 22+ and 4,4’-Bipy. Mo8O264-is connected by Zn (HL) 22+ via terminal oxygen atoms along the [010] axis forming chains, which are further linked by 4 , 4’-Bipy along the [001] axis forming a two-dimensional network structure.