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合成了镧系离子(Ln3+)同己酰水杨酸(Asal)和1.10-二氮杂菲(Phen)的三元配合物并确定其组成为Ln(asal)3·phen.考查了三元配合物的红外光谱、热稳定性和溶解性及其乙醇-水溶液的电子光谱和荧光光谱.
The ternary complex of lanthanide ions (Ln3 +) with hexasalicylic acid (Asal) and 1.10-phenanthroline (Phen) was synthesized and its composition was determined to be Ln (asal) 3 · phen. The infrared spectra, thermal stability and solubility of ternary complexes and the electronic and fluorescence spectra of their ternary complexes were investigated.