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One new polyoxotungstate complex H_6Na_2K_4(H_2W_(12)O_(42))Cl_2·14H_2O 1 has been prepared in the beaker solution and characterized by elemental analysis and IR spectroscopy. Crystal data: H36Cl2K4W12Na2O56, Mr = 3411.77, monoclinic, space group P21/c, a = 11.5734(16), b = 14.3136(19), c = 15.459(2) , β = 105.601(2)°, V = 2466.5(6)3, Z = 2, Dc = 4.594 g/cm3, F(000) = 3008, μ = 28.447 mm-1, R = 0.0574 and wR = 0.1239 (I > 2σ(I)). Single-crystal X-ray diffraction analysis results reveal that a three-dimensional architecture in the title compound is constructed from the H2W12O4210- units linked by potassium.
One new polyoxotungstate complex H_6Na_2K_4 (H_2W_ (12) O_ (42)) Cl_2 · 14H_2O 1 has been prepared in the beaker solution and characterized by elemental analysis and IR spectroscopy. Crystal data: H36Cl2K4W12Na2O56, Mr = 3411.77, monoclinic, space group P21 / a = 11.5734 (16) b = 14.3136 (19) c = 15.459 (2) β β = 105.601 (2) ° V = 2466.5 63 Z = 2 Dc = 4.594 g / Single-crystal X-ray diffraction analysis analysis results reveal that a three-dimensional architecture in the (cm) F (000) = 3008, μ = 28.447 mm-1, R = 0.0574 and wR = 0.1239 title compound is constructed from the H2W12O4210- units linked by potassium.