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The title compound, [Zn(AIP)(4,4-bipy)0.5(H2O)]n·0.75nH2O 1, was synthesized via the hydrothermal reaction of Zn(OAc)2 with 5-aminoisophthalic acid (H2AIP) and characterized by elemental analysis and infrared spectra. The complex crystallizes in monoclinic system, space group P21/c with a = 12.672(1), b = 7.6557(4), c = 16.181(1) , β = 109.187(2)o, V = 1482.6(2) 3, Z = 1, C52H52N8O23Zn4, Mr = 1418.58, Dc = 1.589 g/cm3, F(000) = 724 and μ(MoKα) = 1.685mm-1. The final R = 0.0702 and wR = 0.1524 for 1847 observed reflections with I > 2σ(I), and R = 0.0873 and wR = 0.1664 for all data. X-ray diffraction studies reveal that the title compound has an interesting 2D microporous architecture with guest water molecules inside the channel.
The title compound, [Zn (AIP) (4,4-bipy) 0.5 (H2O)] n · 0.75nH2O 1, was synthesized via the hydrothermal reaction of Zn (OAc) 2 with 5-aminoisophthalic acid (H2AIP) The complex crystallizes in monoclinic system with space group P21 / c with a = 12.672 (1), b = 7.6557 (4), c = 16.181 (1) = 1482.6 (2) 3, Z = 1, C52H52N8O23Zn4, Mr = 1418.58, Dc = 1.589 g / cm3, F (000) = 724 and μ (MoKα) = 1.685mm- 1. The final R = 0.0702 and wR = 0.1524 for 1847 observed reflections with I> 2σ (I), and R = 0.0873 and wR = 0.1664 for all data. X-ray diffraction studies reveal that the title compound has an interesting 2D microporous architecture with guest water molecules inside the channel.