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近年来,由于生物无机化学和材料科学的发展,人们越来越重视多核配合物中磁交换作用的研究,特别是配合物的分子结构与磁性的关系以及磁交换作用的机理。这些研究有助于搞清生物体内电子转移的途径以及氧化还原反应中电子传递的机制,并且为合成具有特殊磁性的材料奠定基础。 Cu(Ⅱ)由于可以形成多种几何构型的配合物,且因其d~9电子组态的理论处理较为简单,
In recent years, due to the development of bio-inorganic chemistry and material science, more and more attention has been paid to the study of magnetic exchange in multi-nuclear complexes, especially the relationship between the molecular structure and magnetic properties of complexes and the mechanism of magnetic exchange. These studies help clarify the pathways of electron transfer in organisms and the mechanisms of electron transfer in redox reactions and lay the foundation for the synthesis of materials with special magnetic properties. Because Cu (Ⅱ) complexes can form many geometric configurations, and the theoretical treatment of d ~ 9 electronic configuration is relatively simple,