论文部分内容阅读
The title compound [2-dapp]2[Zn(dmit)2] synthesized by the direct reaction of [Et4N]2[Zn(dmit)2] and [2-dapp]I crystallizes in monoclinic, space group P2l/c with a = 29.7436(6), b = l0.6266(3), c = l3.6161(4) ? b = 93.l16(l)? V = 4297.3 ?, Z = 4, Dc = 1.448 g/cm3, m = 1.091 mm-1 and F(000) = 1936. The structure was refined by fu1l-matrix 1east-squares methods to the final R = 0.075 and wR = 0.l16, revealing the zinc-bis (dmit) anions interact strongly with the planar cation, 2-dapp+, by the hydrogen bond C(l)H(lC)…S(7) (x, 3/2y, 1/2+z).
The title compound [2-dapp] 2 [Zn (dmit) 2] synthesized by the direct reaction of [Et4N] 2 [Zn (dmit) 2] and [2-dapp] I crystallizes in monoclinic, space group P2l / c with a = 29.7436 (6), b = l0.6266 (3), c = l3.6161 (4)? b = 93.l16 (l)? V = 4297.3 ?, Z = 4, Dc = 1.448 g / cm3, m = 1.091 mm-1 and F (000) = 1936. The structure was refined by fu1l-matrix 1east-squares methods to the final R = 0.075 and wR = 0.l16, revealing the zinc-bis with the planar cation, 2-dapp +, by the hydrogen bond C (1) H (1C) ... S (7) (x, 3 / 2y, 1/2 + z).