Multi-scale decomposition by wavelet transform has been performed to velocity time sequences obtained by fine measurements of turbulent boundary layer flow. A conditional sampling technique for detecting multi-scale coherent eddy structures in turbulent field is proposed by using multi-scale instantaneous intensity factor and flatness factor of wavelet coefficients. Although the number of coherent eddy structures in the turbulent boundary layer is very small, their energy percentage with respect to the turbulence kinetic energy is high. Especially in buffer layer, the energy percentages of coherent structures are significantly higher than those in the logarithmic layer, indicating that the buffer layer is the most active region in the turbulent boundary layer. These multi-scale coherent eddy structures share some common dynamical characteristics and are responsible for the anomalous scaling law in the turbulent boundary layer.